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The transport system has a direct impact on the economic and socio-economic situation of each country. Planning its development is an important element of policy. Bearing in mind the importance and complexity of this issue, it should be considered using both quanti-tative methods and mathematical models, as well as advanced simulation tools for modelling transport. The article presents a proposal for an approach to simulation tests of the national transport system in the aspect of the emission of harmful exhaust gas compounds from road transport. The tool for analysing and assessing the functioning of existing or designed systems is a model in which the properties of the real system, which are important from the point of view of the research objective, should be mapped. We presented formally the Model of Proecological Transport System (MEST) as an ordered four. We presentet also elements of optimization taks shaping of proecological transport system in form of datas, decision variables, conditions and goal function. We shown an example of tests on simulation model.